2-(9H-Fluoren-9-ylidenemethyl)thiophene
نویسندگان
چکیده
The title compound, C(18)H(12)S, contains a thio-phene ring which is disordered by rotation of 180° about the linking C-C bond. The site occupancies of the major and minor components of the disordered ring are 0.900 (3) and 0.100 (3), respectively. In one of these disordered components, the mol-ecule is stabilized by an intra-molecular C-H⋯S hydrogen bond. The compound was synthesized in good yield (80%) by a modified phase-transfer-catalysed condensation of fluorene with thio-phene-2-carbaldehyde.
منابع مشابه
Two Closely Related Organic Charge-Transfer Complexes Based on Tetrathiafulvalene and 9H-fluorenone Derivatives. Competition between Hydrogen Bonding and Stacking Interactions
Two 1:1 charge-transfer organic complexes were formed using tetrathiafulvalene as a donor and a 9H-fluorenone derivative as acceptor: 4,5,7-trinitro-9H-fluoren-9-one-2carboxylic acid (complex 1) or 4,5,7-trinitro-9H-fluoren-9-one-2-carboxylic acid methyl ester (complex 2). Both systems crystallize with alternated donor and acceptor stacks. However, the crystal structure of 1 is influenced by cl...
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